Polymers and Polymer Composites

MOLECULAR TRANSPORT OF AROMATIC HYDROCARBONS THROUGH ETHYLENE PROPYLENE DIENE TERPOLYMER

July 1, 2002 By: Kumar P V A; Varughese K T; Thomas S Research article

Title: MOLECULAR TRANSPORT OF AROMATIC HYDROCARBONS THROUGH ETHYLENE PROPYLENE DIENE TERPOLYMER
Page Range: p.553-568
Author(s): Kumar P V A; Varughese K T; Thomas S
File size: 174K
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Journal: Polymers and Polymer Composites
Issue Year: ppc
Volume: 10
Issue No: No. 7

Abstract
This study reports the diffusivity, sorptivity and permeability of four aromatic hydrocarbons through crosslinked EPDM rubber membranes. Results indicate that the nature of the crosslinking system influences the transport process. Vulcanisation was carried out using four different systems: conventional, efficient, semi-efficient, and sulphurless. The influence of penetrant size on sorption behaviour of EPDM is also examined. From the diffusion data, the activation energies of diffusion and penetration, enthalpy and entropy of sorption, interaction parameter, etc. were evaluated. 21 refs.


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