Polymers and Polymer Composites

Synthesis and characterization of poly(amideimide)s from AB monomers by direct polycondensation using triphenyl phosphite

August 1, 2015 By: Rajasekar S; Venkatesan D Research article

Title: Synthesis and characterization of poly(amideimide)s from AB monomers by direct polycondensation using triphenyl phosphite
Page Range: p.575-582
Author(s): Rajasekar S; Venkatesan D
File size:
Download the pdf (subscribers only)
Buy the pdf (non-subscribers)
Journal: Polymers and Polymer Composites
Issue Year: ppc
Volume: 23
Issue No: No.8

Abstract
Poly(amideimide)s were prepared by the reaction of two new AB monomers, N-(4-aminophenyl)-4-(p-carboxyphenoxy) phthalimide and N-(3-aminophenyl)-4-(p-carboxyphenoxy)phthalimide. The monomers were synthesised by nucleophilic displacement reaction of the corresponding nitrophthalimides with p-hydroxybenzoic acid. The monomers were characterised by IR and NMR. Poly(amideimide)s were prepared from AB monomers by direct polycondensation using triphenyl phosphite. The polymers obtained had high inherent viscosities. The polymers showed high solubility in polar aprotic solvents. The polymers showed good thermal stability and had high glass transition temperatures. X-ray diffraction pattern of the polymers indicate amorphous nature of these polymers. 26 Refs.


Related reading

More journal reading and science coverage connected to this topic.