# SILICON-ORGANIC POLYEPOXIDES WITH EPOXY SIDE GROUPS MODIFIED WITH CHELATES

> Title: SILICON-ORGANIC POLYEPOXIDES WITH EPOXY SIDE GROUPS MODIFIED WITH CHELATES Page Range: p.35-46 Author(s): Lekishvili N; Samakashvili S; Lekishvili G File size: Download the pdf (subscribers only) Buy the pdf (non-subscribers) Journal: Polymers and Polymer Composites Issue Year: ppc Volume: 16 Issue...

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Published: 2008-01-01T00:00:00+00:00
Categories: Polymers and Polymer Composites

**Title: SILICON-ORGANIC POLYEPOXIDES WITH EPOXY SIDE GROUPS MODIFIED WITH CHELATES**
 Page Range: p.35-46
 Author(s): Lekishvili N; Samakashvili S; Lekishvili G
 File size:
 ![](http://dload.gif) [Download the pdf](http://journals.asp?Page=111&JournalDownload=ON&JournalType=ppc&JournalIssue=ppc16-1&JournalID=100416&JIP=) (subscribers only)
 ![](http://handbuy.gif) Buy the pdf (non-subscribers)
 Journal: Polymers and Polymer Composites
 Issue Year: ppc
 Volume: 16
 Issue No: No.1

**Abstract**
 Novel silicon-organic polyepoxides with epoxy side groups attached to the main chain were synthesised by the hydrosilylation of dihydrosiloxanes with a diallyl ether of an epoxidised glycerol. Reaction rate constants and reaction order were determined and the effect of the structure of the monomers with terminal Si-H groups on reaction rate constants, yield and properties of the polyepoxides investigated. The polyepoxides were modified with chelates containing copper, nickel, manganese and cobalt atoms in the main chain and the modified polyepoxides characterised by elemental analysis, IR spectroscopy, NMR spectroscopy, wide angle X-ray diffraction and differential scanning calorimetry. 26 refs.

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