# PHOTOPOLYMERIZATION OF EXO-METHYLENE-1,3-DIOXOLANE WITH BISPHENOL-A-DIGLYCIDYLETHER AND METHYL METHACRYLATE USING PHOTOINITIATORS

> Title: PHOTOPOLYMERIZATION OF EXO-METHYLENE-1,3-DIOXOLANE WITH BISPHENOL-A-DIGLYCIDYLETHER AND METHYL METHACRYLATE USING PHOTOINITIATORS Page Range: p.327-332 Author(s): Sherif M H; Klemm E; Gunther W; Stadermann D File size: 415K Download the pdf (subscribers only) Buy the pdf (non-subscribers) Journal: Polymers and Polymer Composites Issue...

Canonical URL: https://polymerjournals.com/photopolymerization-of-exo-methylene-13-dioxolane-with-bisphenol-a-diglycidylether-and-methyl-methacrylate-using-photoinitiators/
Published: 2001-05-01T00:00:00+00:00
Categories: Polymers and Polymer Composites

**Title: PHOTOPOLYMERIZATION OF EXO-METHYLENE-1,3-DIOXOLANE WITH BISPHENOL-A-DIGLYCIDYLETHER AND METHYL METHACRYLATE USING PHOTOINITIATORS**
 Page Range: p.327-332
 Author(s): Sherif M H; Klemm E; Gunther W; Stadermann D
 File size: 415K
 ![](http://dload.gif) [Download the pdf](http://journals.asp?Page=111&JournalDownload=ON&JournalType=ppc&JournalIssue=ppc9-5&JournalID=99973&JIP=) (subscribers only)
 ![](http://handbuy.gif) Buy the pdf (non-subscribers)
 Journal: Polymers and Polymer Composites
 Issue Year: ppc
 Volume: 9
 Issue No: No. 5

**Abstract**
 The copolymerisation of 2-exo-methylene-4-phenyl,3-dioxolane with bisphenol-A-diglycidylether and methyl methacrylate using a cationic and a radical initiator is described. The structure of the polymers is elucidated by NMR and IR spectroscopy. Using a cationic photoinitiator, the dioxolane structure is maintained in the copolymer and remaining oxirane structures from the bisphenol-A-diglycidylether can be proved. It is demonstrated that no complete ring-opening of the dioxolane takes place in the presence of a radical initiator, leading to statistical polymers with methyl methacrylate. 6 refs.

---
